Chlorine trifluoride is written ClF₃. With school atomic masses the molar mass is 92.5 g/mol. Chlorine trifluoride is a T-shaped molecule of chlorine and three fluorines.
H₂O
WaterNH₃
AmmoniaCO₂
Carbon DioxideH₂O₂
Hydrogen PeroxideSO₂
Sulfur DioxideNO₂
Nitrogen DioxideHCl
Hydrochloric AcidH₂SO₄
Sulfuric AcidHNO₃
Nitric AcidCH₄
MethaneC₂H₆
EthaneC₃H₈
PropaneC₄H₁₀
ButaneC₂H₄
EthyleneC₂H₂
AcetyleneC₆H₆
BenzeneC₇H₈
TolueneC₁₀H₈
NaphthaleneC₆H₁₂
CyclohexaneCH₃OH
MethanolC₂H₅OH
EthanolCH₃COOH
Acetic AcidHCHO
FormaldehydeCH₃COCH₃
AcetoneC₄H₁₀O
Diethyl EtherC₂H₇N
EthylamineC₂H₅NO
AcetamideC₆H₁₂O₆
GlucoseC₆H₁₂O₆
FructoseC₁₂H₂₂O₁₁
SucroseCO(NH₂)₂
UreaC₂₇H₄₆O
CholesterolC₉H₈O₄
AspirinC₈H₉NO₂
AcetaminophenC₁₃H₁₈O₂
IbuprofenC₈H₁₀N₄O₂
CaffeineC₆H₆N₂O
NicotinamideC₆H₈O₆
Ascorbic AcidC₁₆H₁₈N₂O₄S
Penicillin GC₂H₆O₂
Ethylene GlycolC₈H₈
StyreneC₂H₃Cl
Vinyl ChlorideC₃H₅NO
AcrylamideC₆H₁₁NO
CaprolactamLiCl
Lithium chlorideNa₂O
Sodium oxideNaCl
Sodium chlorideMgF₂
Magnesium fluorideAlCl₃
Aluminum chlorideCaO
Calcium oxideCaC₂
Calcium carbideKNO₃
Potassium nitrateMg₃(PO₄)₂
Magnesium phosphateAl₂(SO₄)₃
Aluminum sulfateMg(OH)₂
Magnesium hydroxideNH₄Cl
Ammonium chlorideNH₄OH
Ammonium hydroxideCuO
Copper(II) oxideCu₂O
Copper(I) oxideFeSO₄
Iron(II) sulfateFe₂(SO₄)₃
Iron(III) sulfatePbCO₃
Lead(II) carbonateMgO
Magnesium oxideAl₂S₃
Aluminum sulfideLiF
Lithium fluoride(NH₄)₂S
Ammonium sulfideKF
Potassium fluorideNiCl₂
Nickel(II) chlorideKCN
Potassium cyanideCH₃COONa
Sodium acetateCaCO₃
Calcium carbonateNa₃P
Sodium phosphideBeBr₂
Beryllium bromideFeO
Iron(II) oxideHg₂Cl₂
Mercury(I) chlorideHg(NO₃)₂
Mercury(II) nitrateCH₃COOCu
Copper(I) acetateSiO₂
Silicon dioxideP₄O₁₀
Tetraphosphorus decaoxideN₂O₅
Dinitrogen pentoxideCO
Carbon monoxideHF
Hydrogen fluoridePCl₅
Phosphorus pentachlorideCF₄
Carbon tetrafluorideSF₆
Sulfur hexafluorideNBr₃
Nitrogen tribromideN₂O
Dinitrogen monoxideN₂O₃
Dinitrogen trioxideCS₂
Carbon disulfideCl₂O₇
Dichlorine heptoxideBF₃
Boron trifluorideCCl₄
Carbon tetrachlorideSO₃
Sulfur trioxideSiCl₄
Silicon tetrachlorideP₂S₅
Diphosphorus pentasulfideBCl₃
Boron trichloridePBr₃
Phosphorus tribromideCBr₄
Carbon tetrabromideNF₃
Nitrogen trifluorideOF₂
Oxygen difluorideNCl₃
Nitrogen trichlorideH₂S
Hydrogen sulfidePH₃
PhosphineBeCl₂
Beryllium chlorideHCN
Hydrogen cyanideClF₃
Chlorine trifluorideXeF₂
Xenon difluorideTrigonal bipyramidal
T-shaped
Chlorine trifluoride is a T-shaped molecule of chlorine and three fluorines. Chlorine has two lone pairs; those pairs sit in the equatorial plane, so the bonds look like a T. It is a strong oxidizer and reacts violently with many substances.
Properties
Molar mass
92.45 g/mol
Boiling point
11.8 °C
Bond type
Covalent
Geometry
T-shaped
Uses
T-shaped VSEPR example · Fluorinating reagent
Exam note
Systematic name
Chlorine trifluoride
Compound class
It is a polar covalent molecule. The electron geometry is trigonal bipyramidal and the molecular shape is T-shaped.
Formula unit
Chlorine has five electron groups: three bonds and two lone pairs. The lone pairs occupy equatorial sites, so the bonds form a T.
Watch the formula
With school atomic masses the molar mass is 92.5 g/mol: 35.5 (Cl) + 3×19 (F). Because it is AX₃E₂ the shape is T-shaped, not trigonal planar or pyramidal. It is an interhalogen compound.
Molar mass calculation
Masses given in the question come first. When none are given, school values put the total at 92.5 g/mol.
+
= 92.5 g/mol
ClF₃
The same count with periodic-table atomic masses gives 92.444 g/mol.
| Element | Atom count | Contribution (g/mol) | Mass % |
|---|---|---|---|
| Chlorine (Cl) | 1 | 35.450 | 38.3 |
| Fluorine (F) | 3 | 56.994 | 61.7 |
| Total | 92.444 | 100 |
Common questions
What is chlorine trifluoride?
Chlorine trifluoride is a T-shaped molecule of chlorine and three fluorines. Chlorine has two lone pairs; those pairs sit in the equatorial plane, so the bonds look like a T. It is a strong oxidizer and reacts violently with many substances.
What is the formula of chlorine trifluoride?
Chlorine trifluoride is written ClF₃. The systematic name is Chlorine trifluoride. Chlorine has five electron groups: three bonds and two lone pairs. The lone pairs occupy equatorial sites, so the bonds form a T.
What is the molar mass of chlorine trifluoride?
Chlorine trifluoride has a molar mass of 92.444 g/mol from the atomic masses on the periodic table. With school atomic masses the total is 92.5 g/mol, counting 1 chlorine and 3 fluorine.
What is chlorine trifluoride used for?
Chlorine trifluoride is used for t-shaped VSEPR example and fluorinating reagent.
What should you watch for with chlorine trifluoride on an exam?
With school atomic masses the molar mass is 92.5 g/mol: 35.5 (Cl) + 3×19 (F). Because it is AX₃E₂ the shape is T-shaped, not trigonal planar or pyramidal. It is an interhalogen compound.