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Periodic Table/Rhodium
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45

Rh

102.910

Rhodium

Rodyum

Transition Metal
Period 5
Group 9
Solid

Rhodium is a rare platinum-group metal with atomic number 45. It is best known for catalytic converters, NOx reduction, rhodium plating, high-temperature thermocouples and homogeneous catalysts such as Wilkinson’s catalyst.

Atomic Number

45

Atomic Mass

102.91 g/mol

Electron Configuration

[Kr] 4d⁸ 5s¹

Shells

2 | 8 | 18 | 16 | 1

Electronegativity

2.28

Density

12.41 g/cm³

Melting Point

1963.8 °C

Boiling Point

3694.8 °C

Discovered By

William Hyde Wollaston

History

Rhodium was discovered in 1803 by William Hyde Wollaston while studying crude platinum ores. It was named from the Greek rhodon, meaning rose, because some rhodium salts have a rose-red color.

Isotopes

Rhodium-103

Natural abundance: 100%. The only stable naturally occurring isotope of rhodium.
Important Compounds

RhCl₃

Rhodium(III) ChlorideCatalyst precursor and rhodium plating chemistry.

Rh₂O₃

Rhodium(III) OxideCatalysis and specialty material research.

RhCl(PPh₃)₃

Wilkinson’s CatalystHomogeneous catalyst for alkene hydrogenation.
Uses
  • Three-way catalytic converters, especially for reducing nitrogen oxides
  • Rhodium plating on white gold, silver jewelry and reflective surfaces
  • Platinum-rhodium thermocouples for high-temperature measurement
  • Homogeneous catalysts such as Wilkinson’s catalyst
  • Electrical contacts and corrosion-resistant coatings
Biological Role

Rhodium has no known essential biological role.

Interesting Facts
  • Rhodium is often one of the most expensive precious metals because production is limited and demand from catalytic converters is high.
  • Most rhodium use is tied to automotive emission control.
  • Rhodium-103 makes natural rhodium monoisotopic.
  • Rhodium plating gives jewelry a bright, reflective, corrosion-resistant finish.
Study Notes
  • Rhodium has atomic number 45 and belongs to group 9.
  • Its electron configuration is [Kr] 4d⁸ 5s¹.
  • Rhodium is a platinum-group metal and commonly forms Rh³⁺ compounds.
  • Catalytic converters use rhodium especially for NOx reduction.
Rhodium FAQ
What is the atomic number of rhodium?

The atomic number of rhodium is 45.

What is the electron configuration of rhodium?

Rhodium has the electron configuration [Kr] 4d⁸ 5s¹.

What is rhodium used for?

Rhodium is used in catalytic converters, jewelry plating, thermocouples, catalysts and corrosion-resistant electrical contacts.

Why is rhodium used in catalytic converters?

Rhodium is especially effective for reducing nitrogen oxides in vehicle exhaust.

Is rhodium monoisotopic?

Yes. Natural rhodium consists essentially of stable rhodium-103.

What is Wilkinson’s catalyst?

Wilkinson’s catalyst is a rhodium complex used for homogeneous hydrogenation of alkenes.


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