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Periodic Table/Iridium
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77

Ir

192.220

Iridium

İridyum

Transition Metal
Period 6
Group 9
Solid

Iridium is a dense, corrosion-resistant platinum-group metal with atomic number 77. It is known for iridium spark plugs, Ir-192 brachytherapy, OLED phosphors, oxygen-evolution catalysts and the K-Pg boundary iridium anomaly.

Atomic Number

77

Atomic Mass

192.22 g/mol

Electron Configuration

[Xe] 4f¹⁴ 5d⁷ 6s²

Shells

2 | 8 | 18 | 32 | 15 | 2

Electronegativity

2.2

Density

22.56 g/cm³

Melting Point

2445.8 °C

Boiling Point

4427.9 °C

Discovered By

Smithson Tennant

History

Iridium was discovered in 1803 by Smithson Tennant in platinum ore residues. Its name comes from Iris, the rainbow, because many iridium salts show vivid colors.

Isotopes

Iridium-191

Natural abundance: About 37.3%. Stable natural iridium isotope.

Iridium-192

Half-life: About 73.8 days. Artificial gamma-emitting isotope used in brachytherapy and industrial radiography.

Iridium-193

Natural abundance: About 62.7%. Most abundant stable natural iridium isotope.
Important Compounds

IrO₂

Iridium(IV) OxideHighly active oxygen-evolution catalyst for acidic electrolysis systems.

Ir(ppy)₃

Tris(phenylpyridine)iridiumPhosphorescent emitter used in OLED materials research and displays.

IrCl₃

Iridium(III) ChloridePrecursor for iridium coordination and organometallic catalysts.
Uses
  • Iridium or platinum-iridium spark plug electrodes for long service life
  • Iridium-192 sources for brachytherapy and industrial radiography
  • Iridium oxide catalysts for oxygen evolution in acidic electrolysis
  • Phosphorescent iridium complexes in OLED display materials
  • Corrosion-resistant crucibles, electrodes and high-temperature alloys
Biological Role

Iridium has no known essential biological role. Iridium-192 is used as a sealed radiation source in brachytherapy and industrial radiography under controlled conditions.

Interesting Facts
  • A global iridium-rich layer at the K-Pg boundary helped support the asteroid-impact explanation for the dinosaur extinction event.
  • Iridium is among the most corrosion-resistant metals known.
  • Iridium complexes can harvest triplet excitons, which makes them important in phosphorescent OLED technology.
  • Iridium spark plug tips can be very small because iridium resists melting and erosion.
Study Notes
  • Iridium has atomic number 77 and is a platinum-group metal.
  • Its electron configuration is [Xe] 4f¹⁴ 5d⁷ 6s².
  • Common oxidation states include +3 and +4.
  • Remember iridium for the K-Pg boundary anomaly, spark plugs, Ir-192 and OLED emitters.
Iridium FAQ
What is the atomic number of iridium?

The atomic number of iridium is 77.

What is the electron configuration of iridium?

Iridium has the electron configuration [Xe] 4f¹⁴ 5d⁷ 6s².

What is iridium used for?

Iridium is used in spark plugs, Ir-192 radiation sources, OLED emitters, oxygen-evolution catalysts and corrosion-resistant equipment.

What is the iridium anomaly?

The iridium anomaly is an unusually high iridium concentration at the K-Pg boundary, linked to the asteroid impact associated with dinosaur extinction.

What is iridium-192 used for?

Iridium-192 is used as a sealed gamma source in cancer brachytherapy and industrial radiography.

Why is iridium used in spark plugs?

Iridium has a high melting point and excellent corrosion resistance, helping spark plug electrodes last longer.


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