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Periodic Table/Vanadium
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23

V

50.942

Vanadium

Vanadyum

Transition Metal
Period 4
Group 5
Solid

Vanadium is a transition metal with atomic number 23. It strengthens steel, forms colorful oxidation states, catalyzes sulfuric acid production and is central to vanadium redox flow batteries for grid energy storage.

Atomic Number

23

Atomic Mass

50.942 g/mol

Electron Configuration

[Ar] 3d³ 4s²

Shells

2 | 8 | 11 | 2

Electronegativity

1.63

Density

6.11 g/cm³

Melting Point

1909.8 °C

Boiling Point

3406.8 °C

Discovered By

Andrés Manuel del Río

History

Vanadium was first discovered by Andrés Manuel del Río in 1801, but the discovery was initially dismissed. Nils Gabriel Sefström rediscovered it in 1830 and named it after Vanadis, a Norse goddess associated with beauty, because vanadium compounds can show vivid colors.

Isotopes

Vanadium-51

Natural abundance: About 99.75%. The dominant naturally occurring isotope of vanadium.

Vanadium-50

Natural abundance: About 0.25%. Half-life: About 1.4 x 10¹⁷ years. Extremely long-lived radioactive isotope.
Important Compounds

V₂O₅

Vanadium PentoxideCatalyst for sulfuric acid production and precursor for vanadium battery materials.

VO₂

Vanadium DioxideThermochromic material studied for smart windows.

VOSO₄

Vanadyl SulfateResearch chemical and source of vanadyl ions.

VCl₃

Vanadium(III) ChlorideReducing agent and catalyst precursor.

NH₄VO₃

Ammonium MetavanadateLaboratory precursor for vanadium oxides and catalysts.
Uses
  • Ferrovanadium for strong, tough steels and tool steels
  • Vanadium pentoxide catalyst in the contact process for sulfuric acid production
  • Vanadium redox flow batteries for large-scale energy storage
  • Titanium-aluminum-vanadium alloys such as Ti-6Al-4V
  • Vanadium dioxide smart coatings and thermochromic materials
Biological Role

Vanadium has no confirmed essential role in humans. Some marine organisms concentrate vanadium, and vanadium compounds are studied for biological and metabolic effects.

Interesting Facts
  • Vanadium ions change color with oxidation state: +2 violet, +3 green, +4 blue and +5 yellow.
  • The contact process uses V₂O₅ to catalyze oxidation of SO₂ to SO₃ before sulfuric acid is produced.
  • Vanadium redox flow batteries store energy in liquid electrolytes rather than solid electrodes.
  • Small amounts of vanadium can make steel much stronger and more fatigue-resistant.
Study Notes
  • Vanadium has atomic number 23 and belongs to group 5.
  • Its electron configuration is [Ar] 3d³ 4s².
  • Common oxidation states include +2, +3, +4 and +5.
  • The wide oxidation-state range explains vanadium’s colorful ions, catalytic behavior and redox battery chemistry.
Vanadium FAQ
What is the atomic number of vanadium?

The atomic number of vanadium is 23.

What is the electron configuration of vanadium?

Vanadium has the electron configuration [Ar] 3d³ 4s².

What is vanadium used for?

Vanadium is used in strong steels, titanium alloys, sulfuric acid catalysts, redox flow batteries and smart coating research.

What is a vanadium redox battery?

A vanadium redox battery is a flow battery that stores energy using different oxidation states of vanadium ions in liquid electrolytes.

Why are vanadium compounds colorful?

Vanadium has several accessible oxidation states, and each state can absorb light differently, producing different solution colors.

How is vanadium used in sulfuric acid production?

Vanadium pentoxide catalyzes the oxidation of sulfur dioxide to sulfur trioxide in the contact process.


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