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Periodic Table/Samarium
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62

Sm

150.360

Samarium

Samaryum

Lanthanide
Period 6
Solid

Samarium is a lanthanide with atomic number 62. It is important in samarium-cobalt magnets, neutron absorption, samarium-153 radiopharmaceuticals, SmI₂ organic synthesis and the Sm-Nd geological dating system.

Atomic Number

62

Atomic Mass

150.36 g/mol

Electron Configuration

[Xe] 4f⁶ 6s²

Shells

2 | 8 | 18 | 24 | 8 | 2

Electronegativity

1.17

Density

7.52 g/cm³

Melting Point

1071.8 °C

Boiling Point

1899.8 °C

Discovered By

Lecoq de Boisbaudran

History

Samarium was isolated in 1879 by Paul Émile Lecoq de Boisbaudran from the mineral samarskite. The mineral name honors Vasili Samarsky-Bykhovets, making samarium one of the first elements named through a person’s name.

Isotopes

Samarium-144

Natural abundance: About 3.1%. Stable isotope of samarium.

Samarium-147

Natural abundance: About 15.0%. Half-life: About 1.06 x 10¹¹ years. Alpha-emitting isotope used in Sm-Nd dating.

Samarium-148

Natural abundance: About 11.2%. Half-life: About 6.3 x 10¹⁵ years. Extremely long-lived alpha-emitting isotope of samarium.

Samarium-149

Natural abundance: About 13.8%. Very strong neutron absorber important in reactor physics.

Samarium-150

Natural abundance: About 7.4%. Stable isotope of samarium.

Samarium-152

Natural abundance: About 26.7%. Most abundant natural samarium isotope.

Samarium-153

Half-life: About 46 hours. Beta-emitting medical radioisotope used in Sm-EDTMP.

Samarium-154

Natural abundance: About 22.7%. Stable isotope of samarium.
Important Compounds

SmCo₅

Samarium-Cobalt MagnetHigh-temperature permanent magnet material.

SmI₂

Samarium(II) IodideKagan reagent and one-electron reducing agent in organic synthesis.

Sm₂O₃

Samarium(III) OxideNeutron absorber, glass additive and samarium magnet precursor.

Sm-EDTMP

Samarium-153 EDTMPRadiopharmaceutical for bone pain palliation.
Uses
  • Samarium-cobalt permanent magnets for high-temperature motors, aerospace and defense systems
  • Samarium-153 EDTMP radiopharmaceuticals for bone metastasis pain palliation
  • Samarium(II) iodide, SmI₂, as a one-electron reducing reagent in organic synthesis
  • Neutron absorption in nuclear reactor materials and samarium oxide control applications
  • Sm-Nd isotope dating for ancient rocks, meteorites and lunar samples
Biological Role

Samarium has no essential biological role. Samarium-153 EDTMP has been used as a radiopharmaceutical for pain from bone metastases.

Interesting Facts
  • Samarium-cobalt magnets keep useful magnetic performance at temperatures where many Nd-Fe-B magnets weaken.
  • Samarium-149 is a nuclear reactor poison because it strongly absorbs neutrons.
  • SmI₂ is famous in organic synthesis for enabling single-electron reductions and carbon-carbon bond formation.
  • The Sm-Nd dating system helps determine ages of very old rocks and meteorites.
Study Notes
  • Samarium has atomic number 62 and is a lanthanide.
  • Its electron configuration is [Xe] 4f⁶ 6s².
  • Common samarium chemistry is dominated by +3, but +2 chemistry is important in SmI₂.
  • Remember SmCo magnets, Sm-153 medicine, SmI₂ reagent and Sm-Nd dating.
Samarium FAQ
What is the atomic number of samarium?

The atomic number of samarium is 62.

What is the electron configuration of samarium?

Samarium has the electron configuration [Xe] 4f⁶ 6s².

What is samarium used for?

Samarium is used in samarium-cobalt magnets, neutron absorbers, SmI₂ synthesis chemistry, Sm-153 radiopharmaceuticals and isotope dating.

What are samarium-cobalt magnets?

Samarium-cobalt magnets are strong rare earth permanent magnets valued for high-temperature stability and corrosion resistance.

What is samarium-153 used for?

Samarium-153 EDTMP has been used to relieve pain from bone metastases by delivering beta radiation to affected bone regions.

What is SmI₂?

SmI₂ is samarium(II) iodide, a strong one-electron reducing reagent used in organic synthesis.


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