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Periodic Table/Phosphorus
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15

P

30.974

Phosphorus

Fosfor

Nonmetal
Period 3
Group 15
Solid

Phosphorus is a reactive nonmetal with atomic number 15. It is essential in DNA, RNA, ATP, bones and teeth, and its compounds are widely used in fertilizers, matches, detergents, steel production and special glasses.

Atomic Number

15

Atomic Mass

30.974 g/mol

Electron Configuration

[Ne] 3s² 3p³

Shells

2 | 8 | 5

Electronegativity

2.19

Density

1.82 g/cm³

Melting Point

44.15 °C

Boiling Point

279.9 °C

Discovered By

Hennig Brand

History

Phosphorus was discovered by Hennig Brand in 1669 while experimenting with urine. Its name comes from Greek roots meaning light-bringer, because white phosphorus glows in the dark.

Isotopes

Phosphorus-31

Natural abundance: 100%. The only stable naturally occurring isotope of phosphorus.

Phosphorus-32

Natural abundance: Synthetic. Half-life: About 14.3 days. Radioactive isotope used in biological and medical research.
Allotropes
White Phosphorus (P₄)Highly reactive and toxic molecular allotrope that can ignite in air and glows faintly in the dark.
Red PhosphorusMore stable polymeric form used on safety match striking surfaces.
Black PhosphorusLayered and more stable allotrope studied as a semiconductor and two-dimensional material.
Violet PhosphorusCrystalline Hittorf phosphorus with a complex structure and low reactivity.
Important Compounds

H₃PO₄

Phosphoric AcidUsed in fertilizers, food chemistry and phosphate production.

Ca₃(PO₄)₂

Calcium PhosphateMajor mineral component of bones, teeth and phosphate rocks.

P₄O₁₀

Phosphorus PentoxidePowerful dehydrating agent in chemistry.

PCl₃

Phosphorus TrichlorideReactive chlorinating reagent and precursor for phosphorus chemicals.

PCl₅

Phosphorus PentachlorideChlorinating reagent that illustrates expanded-valence phosphorus chemistry.

Na₃PO₄

Sodium PhosphateUsed in cleaning, water treatment and phosphate chemistry.
Uses
  • Phosphate fertilizers for agriculture
  • Red phosphorus on safety match striking surfaces
  • Phosphates in some detergents, special glasses and ceramics
  • Phosphorus compounds in steel production and chemical manufacturing
  • White phosphorus in flares, smoke devices and specialized military applications
Biological Role

Phosphorus is essential for all living organisms. It forms part of DNA, RNA, ATP and phospholipids, and much of the phosphorus in the human body is stored as calcium phosphate in bones and teeth.

Interesting Facts
  • White phosphorus glows faintly in the dark and is highly dangerous.
  • Red phosphorus is much safer than white phosphorus and is used in safety matches.
  • Black phosphorus has a layered structure and is studied as a two-dimensional semiconductor material.
  • The negative charge of DNA comes from phosphate groups in its sugar-phosphate backbone.
  • ATP, the main energy currency of cells, contains phosphate groups.
Study Notes
  • Phosphorus has atomic number 15 and belongs to group 15.
  • Its electron configuration is [Ne] 3s² 3p³.
  • Phosphorus has five valence electrons and can form several oxidation states.
  • PCl₅ is a classic example used to discuss expanded valence around a third-period central atom.
Phosphorus FAQ
What is the atomic number of phosphorus?

The atomic number of phosphorus is 15.

What is the electron configuration of phosphorus?

Phosphorus has the electron configuration [Ne] 3s² 3p³.

Why is phosphorus important for life?

Phosphorus is found in DNA, RNA, ATP, phospholipids, bones and teeth.

What are the main allotropes of phosphorus?

The main phosphorus allotropes include white phosphorus, red phosphorus, black phosphorus and violet phosphorus.

What is the difference between white and red phosphorus?

White phosphorus is highly reactive and toxic, while red phosphorus is more stable and is used on safety match striking surfaces.

What is phosphorus used for?

Phosphorus is used in fertilizers, safety matches, phosphates, steel production, special glasses and chemical manufacturing.


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