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Periodic Table/Gallium
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31

Ga

69.723

Gallium

Galyum

Post-Transition Metal
Period 4
Group 13
Solid

Gallium is a soft post-transition metal with atomic number 31. It melts near room temperature, forms important semiconductors such as gallium arsenide and gallium nitride, and was one of Mendeleev’s predicted elements.

Atomic Number

31

Atomic Mass

69.723 g/mol

Electron Configuration

[Ar] 3d¹⁰ 4s² 4p¹

Shells

2 | 8 | 18 | 3

Electronegativity

1.81

Density

5.907 g/cm³

Melting Point

29.76 °C

Boiling Point

2203.8 °C

Discovered By

Lecoq de Boisbaudran

History

Gallium was discovered in 1875 by Paul-Émile Lecoq de Boisbaudran using spectroscopy. It closely matched Mendeleev’s predicted eka-aluminum, including density, atomic mass and oxide behavior.

Isotopes

Gallium-69

Natural abundance: About 60.1%. The more abundant stable isotope of gallium.

Gallium-71

Natural abundance: About 39.9%. Stable isotope of gallium.
Important Compounds

GaAs

Gallium ArsenideIII-V semiconductor used in RF electronics, laser diodes, LEDs and high-efficiency solar cells.

GaN

Gallium NitrideWide-bandgap semiconductor used in blue LEDs, white LEDs, lasers and power electronics.

Ga₂O₃

Gallium(III) OxideUltra-wide-bandgap semiconductor studied for high-power and UV devices.

GaCl₃

Gallium(III) ChlorideLewis acid reagent and precursor in gallium chemistry.
Uses
  • Gallium arsenide semiconductors for high-speed electronics, LEDs and solar cells
  • Gallium nitride for blue and white LEDs, laser diodes and power electronics
  • Low-melting alloys such as gallium-indium-tin mixtures
  • Gallium compounds in nuclear medicine and imaging research
  • Thermal interface materials and liquid-metal cooling research
Biological Role

Gallium has no known essential biological role. Ga³⁺ can mimic Fe³⁺ in some biological systems, which is why gallium compounds have been studied in medical and antimicrobial contexts.

Interesting Facts
  • Gallium melts at about 29.8 °C, so it can melt in a warm hand.
  • Gallium nitride blue LEDs helped make efficient white LED lighting possible.
  • Liquid gallium can weaken aluminum by penetrating its grain boundaries.
  • Gallium was a major success for Mendeleev’s periodic table predictions.
Study Notes
  • Gallium has atomic number 31 and belongs to group 13.
  • Its electron configuration is [Ar] 3d¹⁰ 4s² 4p¹.
  • Gallium commonly forms Ga³⁺ and many gallium compounds show +3 oxidation state chemistry.
  • Gallium sits after the 3d transition series, so its chemistry is influenced by the filled 3d¹⁰ subshell.
Gallium FAQ
What is the atomic number of gallium?

The atomic number of gallium is 31.

What is the electron configuration of gallium?

Gallium has the electron configuration [Ar] 3d¹⁰ 4s² 4p¹.

Why does gallium melt in your hand?

Gallium melts near 29.8 °C, which is below normal body temperature, so a warm hand can melt it slowly.

What is gallium used for?

Gallium is used in semiconductors such as GaAs and GaN, LEDs, laser diodes, solar cells, low-melting alloys and research materials.

What is gallium nitride used for?

Gallium nitride is used in blue and white LEDs, laser diodes, high-power electronics and radio-frequency devices.

Why was gallium important for Mendeleev’s periodic table?

Gallium matched Mendeleev’s predicted eka-aluminum, confirming that the periodic table could predict undiscovered elements.


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