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Periodic Table/Bismuth
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83

Bi

208.980

Bismuth

Bizmut

Post-Transition Metal
Period 6
Group 15
Solid

Bismuth is a heavy post-transition metal with atomic number 83. It is known for bismuth subsalicylate, bismuth telluride thermoelectrics, low-melting alloys, colorful oxide crystals and extremely long-lived bismuth-209.

Atomic Number

83

Atomic Mass

208.98 g/mol

Electron Configuration

[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³

Shells

2 | 8 | 18 | 32 | 18 | 5

Electronegativity

2.02

Density

9.807 g/cm³

Melting Point

271.4 °C

Boiling Point

1563.8 °C

Discovered By

Claude François Geoffroy

History

Bismuth was known to miners and metalworkers for centuries, but it was clearly distinguished from lead and tin in the 18th century. Its name likely comes from the German Wismut.

Isotopes

Bismuth-209

Natural abundance: 100%. Half-life: About 1.9 x 10¹⁹ years. Extremely long-lived alpha emitter, effectively stable for practical chemistry.

Bismuth-213

Half-life: About 45.6 minutes. Artificial isotope studied for targeted alpha therapy.
Important Compounds

BiC₇H₅O₄·H₂O

Bismuth SubsalicylateActive ingredient in digestive medicines such as Pepto-Bismol.

Bi₂Te₃

Bismuth TellurideThermoelectric material for Peltier coolers and waste-heat devices.

BiVO₄

Bismuth VanadateBright yellow pigment and photocatalysis research material.

Bi₂O₃

Bismuth(III) OxideGlass, ceramics, catalysts and electronic materials.
Uses
  • Bismuth subsalicylate in over-the-counter digestive medicines
  • Bismuth telluride thermoelectric coolers and generators
  • Low-melting alloys for fuses, fire sprinklers and special casting materials
  • Bismuth vanadate yellow pigment as a safer alternative to some heavy-metal pigments
  • Bismuth radioisotopes in targeted alpha therapy research
Biological Role

Bismuth has no essential biological role, but many bismuth compounds have relatively low toxicity compared with other heavy metals. Bismuth subsalicylate is used in digestive medicines.

Interesting Facts
  • Bismuth-209 was long considered stable until its extremely slow alpha decay was measured.
  • Bismuth expands slightly as it solidifies, a rare behavior among metals.
  • Bismuth crystals can show rainbow colors because thin oxide layers create optical interference.
  • Bismuth compounds often replace more toxic lead compounds in some applications.
Study Notes
  • Bismuth has atomic number 83 and symbol Bi.
  • Its electron configuration is [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³.
  • The +3 oxidation state is most common; +5 is less stable because of the inert pair effect.
  • Remember bismuth for subsalicylate medicine, Bi₂Te₃ thermoelectrics and long-lived Bi-209.
Bismuth FAQ
What is the atomic number of bismuth?

The atomic number of bismuth is 83.

What is the electron configuration of bismuth?

Bismuth has the electron configuration [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³.

What is bismuth used for?

Bismuth is used in digestive medicines, thermoelectric materials, low-melting alloys, pigments and research radioisotopes.

Is bismuth radioactive?

Natural bismuth is bismuth-209, which is an extremely long-lived alpha emitter and is effectively stable in ordinary chemistry.

What is bismuth subsalicylate?

Bismuth subsalicylate is a bismuth compound used in medicines for upset stomach and diarrhea symptoms.

Why are bismuth crystals colorful?

Thin oxide layers on bismuth crystals create interference colors, producing rainbow-like surfaces.


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