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Periodic Table/Arsenic
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33

As

74.922

Arsenic

Arsenik

Metalloid
Period 4
Group 15
Solid

Arsenic is a toxic metalloid with atomic number 33. It is known for arsenic poisoning, semiconductor compounds such as gallium arsenide, historical pigments, allotropes and environmental groundwater contamination.

Atomic Number

33

Atomic Mass

74.922 g/mol

Electron Configuration

[Ar] 3d¹⁰ 4s² 4p³

Shells

2 | 8 | 18 | 5

Electronegativity

2.18

Density

5.727 g/cm³

Melting Point

816.9 °C

Boiling Point

886.9 °C

Discovered By

Albertus Magnus

History

Arsenic compounds were known in antiquity as pigments and poisons. Metallic arsenic is often associated with Albertus Magnus in the 13th century, and arsenic later became famous in the history of toxicology and forensic chemistry.

Isotopes

Arsenic-75

Natural abundance: 100%. The only stable naturally occurring isotope of arsenic.
Allotropes
Gray ArsenicMost stable metallic-looking allotrope with a rhombohedral structure and semimetal behavior.
Yellow ArsenicMolecular As₄ form that is unstable and can transform into gray arsenic.
Black ArsenicAmorphous or layered form produced under special conditions and less common than gray arsenic.
Important Compounds

As₂O₃

Arsenic TrioxideHighly toxic compound with controlled medical use in acute promyelocytic leukemia treatment.

AsH₃

ArsineVery toxic gas used in semiconductor doping and specialty synthesis.

As₂S₃

Arsenic TrisulfideOrpiment mineral, historical yellow pigment and infrared glass material.

As₄S₄

RealgarRed-orange arsenic sulfide mineral historically used as pigment.

GaAs

Gallium ArsenideIII-V semiconductor used in RF electronics, LEDs and solar cells.
Uses
  • Gallium arsenide semiconductors for electronics and optoelectronics
  • Arsenic trioxide in specific cancer treatment protocols such as acute promyelocytic leukemia
  • Historical pigments such as orpiment and realgar
  • Specialty glass and semiconductor doping applications
  • Lead alloy hardening in limited specialized uses
Biological Role

Arsenic has no confirmed essential role in humans. Inorganic arsenic is toxic and carcinogenic, while a few arsenic compounds have specialized medical uses under strict control.

Interesting Facts
  • Arsenic-75 is monoisotopic, so natural arsenic has one stable isotope.
  • Arsenic contamination of groundwater is a major environmental health problem in some regions.
  • The Marsh test was an early forensic chemistry method for detecting arsenic.
  • Gray arsenic is the most stable allotrope under ordinary conditions.
Study Notes
  • Arsenic has atomic number 33 and belongs to group 15.
  • Its electron configuration is [Ar] 3d¹⁰ 4s² 4p³.
  • Arsenic is a metalloid and commonly shows oxidation states -3, +3 and +5.
  • Toxicity depends strongly on chemical form; inorganic arsenic compounds are especially hazardous.
Arsenic FAQ
What is the atomic number of arsenic?

The atomic number of arsenic is 33.

What is the electron configuration of arsenic?

Arsenic has the electron configuration [Ar] 3d¹⁰ 4s² 4p³.

Is arsenic toxic?

Yes. Inorganic arsenic compounds are toxic and carcinogenic, so exposure must be carefully controlled.

What are the main allotropes of arsenic?

Important arsenic allotropes include gray arsenic, yellow arsenic and black arsenic.

What is gallium arsenide used for?

Gallium arsenide is a semiconductor used in RF electronics, LEDs, laser diodes and high-efficiency solar cells.

What is arsenic used for?

Arsenic is used in specialized semiconductors, controlled medical compounds, some historical pigments and limited alloy or glass applications.


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