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Periodic Table/Fluorine
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9

F

18.998

Fluorine

Flor

Halogen
Period 2
Group 17
Gas

Fluorine is a pale yellow halogen gas and the most electronegative chemical element. It is extremely reactive and is important in fluorides, fluoropolymers such as PTFE, uranium hexafluoride, dental chemistry and PET imaging.

Atomic Number

9

Atomic Mass

18.998 g/mol

Electron Configuration

[He] 2s² 2p⁵

Shells

2 | 7

Electronegativity

3.98

Density

1.55e-3 g/cm³

Melting Point

-219.7 °C

Boiling Point

-188.1 °C

Discovered By

Henri Moissan

History

Fluorine was isolated by Henri Moissan in 1886 after many difficult and dangerous attempts by earlier chemists. Its name is related to fluorspar, a mineral containing calcium fluoride.

Isotopes

Fluorine-19

Natural abundance: 100%. The only stable naturally occurring isotope of fluorine.

Fluorine-18

Natural abundance: Synthetic. Half-life: About 110 minutes. Radioactive isotope used in PET imaging.
Important Compounds

HF

Hydrogen FluorideUsed to produce hydrofluoric acid for glass etching and fluorine chemistry.

NaF

Sodium FluorideUsed in dental products and water fluoridation in controlled amounts.

CaF₂

Calcium FluorideNatural mineral fluorite used as a source of fluorine compounds.

SF₆

Sulfur HexafluorideElectrical insulating gas with a very high global warming potential.

PTFE

PolytetrafluoroethyleneFluoropolymer used in non-stick coatings and chemically resistant materials.

UF₆

Uranium HexafluorideUsed in uranium enrichment processes.
Uses
  • Fluoride compounds in toothpaste and dental health applications
  • PTFE and other fluoropolymers used in non-stick and chemical-resistant materials
  • Uranium hexafluoride for uranium enrichment
  • Hydrofluoric acid for glass etching and industrial chemistry
  • Fluorine-18 radiotracers for PET medical imaging
Biological Role

Elemental fluorine has no biological role and is highly toxic. Fluoride ions in controlled amounts help protect tooth enamel, while excessive fluoride exposure can be harmful.

Interesting Facts
  • Fluorine is the most electronegative element.
  • Fluorine reacts with many substances very vigorously.
  • Hydrofluoric acid is a weak acid by dissociation, but it is highly dangerous because fluoride can penetrate tissue and bind calcium ions.
  • Fluoride and fluorine are not the same: fluoride is the ion F⁻, while fluorine is the element.
Study Notes
  • Fluorine has atomic number 9 and belongs to group 17.
  • Its electron configuration is [He] 2s² 2p⁵.
  • Fluorine has seven valence electrons and commonly forms F⁻.
Fluorine FAQ
What is the atomic number of fluorine?

The atomic number of fluorine is 9.

What is the electron configuration of fluorine?

Fluorine has the electron configuration [He] 2s² 2p⁵.

Why is fluorine important?

Fluorine is important in fluoride dental chemistry, fluoropolymers, uranium hexafluoride, hydrofluoric acid and PET imaging isotopes.

Is fluorine the most electronegative element?

Yes. Fluorine is the most electronegative element on the Pauling scale.

What is the difference between fluorine and fluoride?

Fluorine is the chemical element, while fluoride is the F⁻ ion found in many salts and dental products.

Why is hydrofluoric acid dangerous?

Hydrofluoric acid is dangerous because fluoride can penetrate tissue and bind calcium ions, even though HF is weakly dissociated in water.


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